Hammer Juice Solvents, Alcohols, Long

Earl S. Dunlap, Jr. dunlapes@home.com
Thu, 06 Sep 2001 19:56:15 -0400


List:

In case it helps when you make your choices ethanol is "grain alcohol" and
will not contain less than 5% water when water is boiled out of it to
concentrate it from mash since water and ethanol form a "constant boiling
mixture" at 5/95 percents, respectively, of each. This means one cannot make
ethanol stronger than 95% when boiled just with water .  Ethanol can be made
to go to 100%, I believe by boiling with benzene (highly toxic).  It would
then be called "absolute" ethanol although there would be residual benzene.

The U.S. Government permits use of several formulas (schedules) using fixed
percentages added to ethanol of various chemicals so it is "denatured" or
made undrinkable (poisonous) and thus not taxed as drinkable alcohol.  These
formulae are different enough that some may work better for some industrial
purposes than others:  yours?

Some could conceivably be made back into drinkable form more easily than
others (none easily.)  E.g., one of these uses methanol or as the only
denaturant.  For this reason the BATF (Bureau of Alcohol Tax and Firearms)
requires--or at least used to require--special handling/permitting for this
grade.  This may be available to you; you could call the BATF for information.

"Wood alcohol," methanol, is easily obtainable as 100%, and both this and
denatured ethanol are sure to be cheaper than 190 proof drinking alcohol.
Methanol may work well to dissolve shellac, but methanol vapor at any
significant concentration air would be something I certainly wouldn't
recommend.  

The denaturant formulas in ethanol (and possibly colorant) may possibly be a
problem for piano technicians.  The denaturants are indeed toxic, but are in
low concentrations.  Depending upon ventilation and quantity used they may
not give you difficulty.  Again, 5% water is present in all grades unless
sold as "absolute" ethanol.

If you feel you need more info. all the people that sell alcohol--for that
matter, all chemicals:  and what isn't a chemical?-- must be prepared to
supply those that request it an MSDS, a Material Safety Data Sheet, that
tells more than you'll want to know about that chemical.  You may call the
chemical manufacturer's number (or the state or federal EPA if you get a
hard time)! 

When you read the MSDS, you'll be scared to death.  Their respective MSDS'
make aspirin and table salt to appear as terrible poisons: and don't bother
reading the one on saccharin!  I'd guess this "crying wolf" is to minimize
potential legal problems for the manufacturer.

By the way, any of these alcohols are very water soluble (as is acetone
(very much more volatile & thus more flammable) or methyl ethyl ketone (a
bit less so)), and when they evaporate rapidly, will chill the area drawing
moisture from the air--more so in humid climates.  This moisture has the
potential to release the press in the wool!  (Re:  Susan Kline's correct
"steam in a bottle" comment on 04 Sep 2001 18:30:15)

I could say lots more but I'm sure you're sick of it by now.  Apologies.
Thanks for your patience.

Keep on doing the great jobs you're doing, RPTs.

Earl Dunlap, Textile Chemist and lurker (with your kind permission)




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