<html xmlns:v="urn:schemas-microsoft-com:vml" =
xmlns:o="urn:schemas-microsoft-com:office:office" =
xmlns:w="urn:schemas-microsoft-com:office:word" =
xmlns:st1="urn:schemas-microsoft-com:office:smarttags" =
xmlns="http://www.w3.org/TR/REC-html40">
<head>
<meta http-equiv=Content-Type content="text/html; =
charset=us-ascii">
<meta name=ProgId content=Word.Document>
<meta name=Generator content="Microsoft Word 11">
<meta name=Originator content="Microsoft Word 11">
<link rel=File-List href="cid:filelist.xml@01C5A346.F0D3AE90">
<link rel=Edit-Time-Data href="cid:editdata.mso">
<!--[if !mso]>
<style>
v\:* {behavior:url(#default#VML);}
o\:* {behavior:url(#default#VML);}
w\:* {behavior:url(#default#VML);}
.shape {behavior:url(#default#VML);}
</style>
<![endif]--><o:SmartTagType
namespaceuri="urn:schemas-microsoft-com:office:smarttags" =
name="PersonName"/>
<!--[if gte mso 9]><xml>
<o:OfficeDocumentSettings>
<o:DoNotRelyOnCSS/>
</o:OfficeDocumentSettings>
</xml><![endif]--><!--[if gte mso 9]><xml>
<w:WordDocument>
<w:DontDisplayPageBoundaries/>
<w:SpellingState>Clean</w:SpellingState>
<w:GrammarState>Clean</w:GrammarState>
<w:DocumentKind>DocumentEmail</w:DocumentKind>
<w:EnvelopeVis/>
<w:ValidateAgainstSchemas/>
<w:SaveIfXMLInvalid>false</w:SaveIfXMLInvalid>
<w:IgnoreMixedContent>false</w:IgnoreMixedContent>
<w:AlwaysShowPlaceholderText>false</w:AlwaysShowPlaceholderText>
</w:WordDocument>
</xml><![endif]--><!--[if gte mso 9]><xml>
<w:LatentStyles DefLockedState="false" LatentStyleCount="156">
</w:LatentStyles>
</xml><![endif]--><!--[if !mso]>
<style>
st1\:*{behavior:url(#default#ieooui) }
</style>
<![endif]-->
<style>
<!--
/* Font Definitions */
@font-face
        {font-family:Tahoma;
        panose-1:2 11 6 4 3 5 4 4 2 4;
        mso-font-charset:0;
        mso-generic-font-family:swiss;
        mso-font-pitch:variable;
        mso-font-signature:553679495 -2147483648 8 0 66047 0;}
@font-face
        {font-family:Verdana;
        panose-1:2 11 6 4 3 5 4 4 2 4;
        mso-font-charset:0;
        mso-generic-font-family:swiss;
        mso-font-pitch:variable;
        mso-font-signature:536871559 0 0 0 415 0;}
/* Style Definitions */
p.MsoNormal, li.MsoNormal, div.MsoNormal
        {mso-style-parent:"";
        margin:0in;
        margin-bottom:.0001pt;
        mso-pagination:widow-orphan;
        font-size:12.0pt;
        font-family:"Times New Roman";
        mso-fareast-font-family:"Times New Roman";
        color:windowtext;}
a:link, span.MsoHyperlink
        {color:blue;
        text-decoration:underline;
        text-underline:single;}
a:visited, span.MsoHyperlinkFollowed
        {color:purple;
        text-decoration:underline;
        text-underline:single;}
p
        {mso-margin-top-alt:auto;
        margin-right:0in;
        mso-margin-bottom-alt:auto;
        margin-left:0in;
        mso-pagination:widow-orphan;
        font-size:12.0pt;
        font-family:"Times New Roman";
        mso-fareast-font-family:"Times New Roman";
        color:black;}
span.EmailStyle17
        {mso-style-type:personal-reply;
        mso-style-noshow:yes;
        mso-ansi-font-size:10.0pt;
        mso-bidi-font-size:10.0pt;
        font-family:Arial;
        mso-ascii-font-family:Arial;
        mso-hansi-font-family:Arial;
        mso-bidi-font-family:Arial;
        color:navy;}
span.SpellE
        {mso-style-name:"";
        mso-spl-e:yes;}
span.GramE
        {mso-style-name:"";
        mso-gram-e:yes;}
@page Section1
        {size:8.5in 11.0in;
        margin:1.0in 1.25in 1.0in 1.25in;
        mso-header-margin:.5in;
        mso-footer-margin:.5in;
        mso-paper-source:0;}
div.Section1
        {page:Section1;}
-->
</style>
<!--[if gte mso 10]>
<style>
/* Style Definitions */
table.MsoNormalTable
        {mso-style-name:"Table Normal";
        mso-tstyle-rowband-size:0;
        mso-tstyle-colband-size:0;
        mso-style-noshow:yes;
        mso-style-parent:"";
        mso-padding-alt:0in 5.4pt 0in 5.4pt;
        mso-para-margin:0in;
        mso-para-margin-bottom:.0001pt;
        mso-pagination:widow-orphan;
        font-size:10.0pt;
        font-family:"Times New Roman";
        mso-ansi-language:#0400;
        mso-fareast-language:#0400;
        mso-bidi-language:#0400;}
</style>
<![endif]-->
</head>
<body lang=EN-US link=blue vlink=purple =
style='tab-interval:.5in'>
<div class=Section1>
<p class=MsoNormal><font size=2 color=navy face=Arial><span =
style='font-size:
10.0pt;font-family:Arial;color:navy'>As to the first point, Susan, NO!! =
<span
class=GramE>(Thankfully!)</span><span =
style='mso-spacerun:yes'> </span>To
quote a Ph.D. in the field (I’m more food/flavor =
chemistry):<o:p></o:p></span></font></p>
<p class=MsoNormal><font size=2 color=navy face=Arial><span =
style='font-size:
10.0pt;font-family:Arial;color:navy'><o:p> </o:p></span></font></p>
<p><span class=SpellE><font size=1 color=black =
face=Verdana><span
style='font-size:7.5pt;font-family:Verdana'>Cyanoacrylate</span></font>=
</span><font
size=1 face=Verdana><span =
style='font-size:7.5pt;font-family:Verdana'> glues
contain the group H2C=CH-CN: Where the = represents a double bond =
between two
carbons and there is a triple bond between the carbon and nitrogen of =
the CN.
CN is the '<span class=SpellE>cyano</span>' group, and a three-carbon =
chain
with a double bond next to another type of multiple bond (or some other =
form of
electron rich group such as a radical or anion) is an 'acrylic' group -- =
the
combination gives a relatively high reactivity to the compounds and =
allows them
to polymerize like a plastic. Many non-toxic compounds contain both =
types of
groups, and many medicines have <span class=SpellE>cyano</span> =
groups. Along
with this group, there are other chemicals and can be other chains =
attached to
that <span class=SpellE>cyanoacrylate</span> group in place of one or =
more of
the <span =
class=SpellE>hydrogens</span>. </span></font><o:p></o:p></p>
<p><font size=1 color=black face=Verdana><span =
style='font-size:7.5pt;
font-family:Verdana'>There is NO, NONE, NADA cyanide released on curing =
these
glues and hardening. There are some obnoxious fumes released -- some of =
them
just parts that boil out from the heat of the curing reaction. BUT, =
whenever an
organic chemical that contains nitrogen is burned, some <span =
class=SpellE>cyanogen</span>/hydrogen
cyanide is released. This happens with tobacco, meat, veggies, fireplace =
wood,
etc. This release is worst when there is not enough oxygen present in =
the
burning zone to ensure complete combustion -- so if there is a lot of =
smoke
formation, there is more <span class=SpellE>likelyhood</span> of =
cyanide
formation.<o:p></o:p></span></font></p>
<p><font size=3 color=black face="Times New Roman"><span =
style='font-size:12.0pt'>Sorry
if that’s more chemistry than you wanted, but I think it makes the =
point.
<span style='mso-spacerun:yes'> </span>Watch out for smoking =
rags, etc! <o:p></o:p></span></font></p>
<p><font size=3 color=black face="Times New Roman"><span =
style='font-size:12.0pt'>To
the “kicker” issue, I assume that’s an =
accelerant?<span
style='mso-spacerun:yes'> </span>Anything with water (a VERY =
WEAK lye
solution would be better) is going to work. <span
style='mso-spacerun:yes'> </span>Elmer’s may just be =
getting in the
way of the polymerization. <span =
style='mso-spacerun:yes'> </span>How is
the smell irritating (acrid, ammonia, etc)?<span
style='mso-spacerun:yes'> </span>That may give some indication =
of what’s
going on. <o:p></o:p></span></font></p>
<p><font size=3 color=black face="Times New Roman"><span =
style='font-size:12.0pt'>John
Delmore<o:p></o:p></span></font></p>
<p class=MsoNormal><font size=2 color=navy face=Arial><span =
style='font-size:
10.0pt;font-family:Arial;color:navy'><o:p> </o:p></span></font></p>
<div>
<div class=MsoNormal align=center style='text-align:center'><font =
size=3
face="Times New Roman"><span style='font-size:12.0pt'>
<hr size=2 width="100%" align=center tabindex=-1>
</span></font></div>
<p class=MsoNormal><b><font size=2 face=Tahoma><span =
style='font-size:10.0pt;
font-family:Tahoma;font-weight:bold'>From:</span></font></b><font =
size=2
face=Tahoma><span style='font-size:10.0pt;font-family:Tahoma'>
pianotech-bounces@ptg.org [mailto:pianotech-bounces@ptg.org] <b><span
style='font-weight:bold'>On Behalf Of </span></b>Susan Kline<br>
<b><span style='font-weight:bold'>Sent:</span></b> Wednesday, August =
17, 2005
3:28 PM<br>
<b><span style='font-weight:bold'>To:</span></b> <st1:PersonName =
w:st="on">Pianotech</st1:PersonName><br>
<b><span style='font-weight:bold'>Subject:</span></b> RE: CA =
Glue</span></font><o:p></o:p></p>
</div>
<p class=MsoNormal><font size=3 face="Times New Roman"><span =
style='font-size:
12.0pt'><o:p> </o:p></span></font></p>
<p class=MsoNormal><font size=3 face="Times New Roman"><span =
style='font-size:
12.0pt'>At 01:54 PM 8/17/2005 -0500, you wrote:<br>
<br style='mso-special-character:line-break'>
<![if !supportLineBreakNewLine]><br =
style='mso-special-character:line-break'>
<![endif]><o:p></o:p></span></font></p>
<p class=MsoNormal><font size=2 color=navy face=Arial><span =
style='font-size:
10.0pt;font-family:Arial;color:navy'>The CA glues themselves have very =
low
toxicity. And although some companies (Sur-Lok, for one) market =
their
products as solvent free, most are 99% methyl or ethyl =
cyanoacrylate
(butyl and octyl cyanoacrylates are used for surgical closures, an =
indication
of their low toxicity!). Of the two, I would look for one that is =
ethyl
cyanoacrylate, as a little safer than the methyl. Maybe fewer
fumes. But the fumes, though not terribly toxic, are =
irritants. So
keep up with the ventilation. As for safety, anything that works =
this
good, ya gotta be careful with!<br>
</span></font><br>
<font size=2 color=navy face=Arial><span =
style='font-size:10.0pt;font-family:
Arial;color:navy'>John Delmore</span></font><o:p></o:p></p>
<p class=MsoNormal><font size=2 face=Arial><span =
style='font-size:10.0pt;
font-family:Arial'><br>
</span></font>This is very interesting, John. I've heard rumors that =
while
curing CA glue can emit small amounts of cyanide? Is this true? <br>
<br>
Also, can you tell us what is so very irritating about the kicker? One =
smell
and I decided not to use it. And is the bond stronger or weaker if the =
glue is
"kicked"? I "kick" by using it along with white glue
(Elmer's), but the effect seems much less violent than the spray-on =
kicker
which is sold for the purpose. <br>
<br>
Thanks for letting us pick your brains ... <br>
<br>
Susan Kline <o:p></o:p></p>
</div>
</body>
</html>