Silicone creep

Tim Keenan & Rebecca Counts tkeenan@kermode.net
Tue, 17 Mar 1998 21:47:26 -0800


ralph m martin wrote:
> 

> Some of the houses selling furniture touch-up supplies also list mineral
> spirits for the removal of silicone

in response to Mike Swendsen's> 

> >The only solvent that will clean silicone is naphtha......
> >try that and you might be able to glue the parts....
> >maybe

In fact, any non-polar solvent will do the job--the more non-polar the 
better [water is very polar, alkanes are non-polar, and alcohols are in 
between.] That means alcohols are not too good, and the heavier alcohols 
(propanol, butanol, etc) are better than the lighter ones (methanol and 
ethanol), but will have the unfortunate tendency to form hydrogen bonds 
with the cellulose in the wood --bad idea--polyethylene glycol is a heavy 
alcohol. Lower molecular weight alkanes like naphtha (kudos to Mike for 
spelling) are good candidates. If you want really good performance at some 
risk to your health and that of the environment and the ozone layer, try 
perchloroethylene or methylene chloride.  The trick, if you are removing 
silicone oil from a finished surface, is not to dissolve the finish too.  
That is probably the reason furniture types recommend the less aggressive 
mineral spirits.  I think that when you are talking about gluing, however, 
you are probably talking about an unfinished surface in most cases, and 
there you have a problem.  You can probably never practically remove *all* 
the silicone oil from a piece of unfinished wood once it is contaminated.  
You may be able to remove enough to get a good glue bond, but it will 
require several washings in the solvent of your choice.  Many tropical 
hardwoods are notoriously difficult to glue because of their high oil 
content (teak in particular), but they can be treated in this way, just on 
the surface to be glued, and once the glue has penetrated the temporarily 
oil-free cells on the gluing surface and set, it cannot be subsequently 
displaced by the oil leaching back in from cells deeper down (presuming the 
cured glue is not soluble in the oil in question).

(--i studied wood technology as well as chemistry and biology in a former 
life--

Tim Keenan, 
Terrace BC


This PTG archive page provided courtesy of Moy Piano Service, LLC